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Architecture, Civil Engineering, Environment

Silesian University of Technology

Subject: Architecture, Civil Engineering, Engineering, Environmental


ISSN: 1899-0142





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VOLUME 9 , ISSUE 4 (December 2016) > List of articles



Keywords : Fenton reagent, UV-Fenton, Acid Green 16, sodium percarbonate, Discoloration

Citation Information : Architecture, Civil Engineering, Environment. Volume 9, Issue 4, Pages 135-140, DOI: https://doi.org/10.21307/acee-2016-060

License : (BY-NC-ND 4.0)

Received Date : 18-October-2016 / Accepted: 07-November-2016 / Published Online: 27-August-2018



A modified Fenton process using sodium percarbonate (SP), as an alternative source of H2O2, and UV radiation was investigated to discoloration of dye wastewater containing Acid Green 16 (concentration 100 mg/dm3). This acid dye is characterized by the harmful effect on aquatic organisms and it may cause adverse effects in the aquatic environment. The experiments were carried out in two systems, in which two lamps were used as a UV radiation source: low pressure (system I) and medium pressure (system II). The effect of SP dosage (100-400 mg/dm3 – system I; and 100-250 mg/dm3 – system II), Fe2+/SP ratio (from 0.2 to 0.4), reaction pH (3 and 4) and reaction time (from 10 to 30 min) on colour removal efficiency was examined. The modified Fenton process was found to be very efficient for discoloration of simulated wastewater. For a system with a low pressure UV lamp the optimal doses of SP and Fe2+/SP ratio were 400 mg/dm3 and 0.2, respectively at pH 3 and 20 minutes reaction time. For a system with a medium pressure UV lamp the optimal doses of SP and Fe2+/SP ratio were 200 mg/dm3 and 0.33, respectively at pH 3 and 20 minutes reaction time. In both cases, at described conditions total visual discoloration was achieved. Better results of colour removal (concentration of Acid Green 16 was in the range of 0.64-0.96 mg/dm3) were achieved when the initial pH value equalled 3.0 than at initial pH value of 4.0 (concentration of Acid Green 16 was in the range of 0.80-6.87 mg/dm3).

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[1] Kyzioł-Komosińska J., Rosik-Dulewska Cz., Pająk M., Czupioł J., Dzieniszewska A., Krzyżewska J.; Sorption of Acid Green 16 from aqueous solution onto lowmoor peat and smectite clay co-occurring in lignite of Belchatow mine field. Annual Set The Environment Protection, Vol.17, 2015; pp.165-187

[2] Barbusiński K.; Fenton reaction – Controversy concerning the chemistry. Ecological Chemistry and Engineering (S), Vol.16, No.3, 2009; pp.347-358

[3] Barbusiński K., Fajkis S.; Optimization of the Fenton oxidation of wastewater generated by rape oil soapstock splitting. Environ. Prog. Sustainable Energy, Vol.30, No.4, 2011; pp.620-631 (doi: 10.1002/ep.10525)

[4] Qiong Yu Liu, Yan Xiang Liu, Xu Jie LU; Combined photo-Fenton and biological oxidation for the treatment of aniline wastewater. Procedia Environmental Sciences, Vol.12, 2012; pp.341-348 (doi: 10.1016/j.proenv.2012.01.287)

[5] Yuehua Zhang, Zhiwen Luo, Tingru Pan, Changhong Guo; Degradation oxidation applied to the acetochlor in aqueous solutions with potassium peroxymonopersulfate with Fenton’s reagent. Procedia Environmental Sciences, Vol.16, 2012; pp.266-270 (doi: 10.1016/j.proenv.2012. 10.037)

[6] Barbusiński K., Filipek K.; Use of Fenton’s reagent for removal of pesticides from industrial wastewater. Polish J. Environ. Stud., Vol.10, No.4, 2001; pp.207-212

[7] Karci A., Arslan-Alatonb I., Bekbolet M.; Advanced oxidation of a commercially important nonionic surfactant: Investigation of degradation products and toxicity. J. Hazard. Mat., Vol.263, 2013; pp.275-282

[8] Panizza M., Barbucci A., Delucchi M., Carpanese M.P., Giuliano A., Cataldo-Hernández M., Cerisola G.; Electro-Fenton degradation of anionic surfactants. Separation and Purification Technology, Vol.118, 2013; pp.394-398

[9] Chia-Chi Su, Massakul Pukdee-Asa, Chavalit Ratanatamskul, Ming-Chun Lu; Effect of operating parameters on decolorization and COD removal of three reactive dyes by Fenton’s reagent using fluidized-bed reactor. Desalination, Vol.278, 2011; pp.211-218

[10] Elhalil A., Tounsadi H., Elmoubarki R., Mahjoubi F.Z., Farnane M., Sadiq M., Abdennouri M., Qourzal S., Barka N.; Factorial experimental design for the optimization of catalytic degradation of malachite green dye in aqueous solution by Fenton process. Water Resources and Industry, Vol.15, 2016; pp.41-48

[11] Barbusinski K., Filipek K.; Aerobic sludge digestion in the presence of chemical oxidizing agents part II. Fenton’s reagent. Polish J. Environ. Stud., Vol.9, No.3, 2000; pp.145-149

[12] Barbusinski K., Filipek K.; Aerobic sludge digestion in the presence of hydrogen peroxide and Fenton’s reagent. Polish J. Environ. Stud., Vol.12, No.1, 2003; pp.35-40

[13] Barbusinski K., Salwiczek S.; Use of Fenton reagent and the UV/H2O2 method for removal of organic compounds from wastewater from 2-ethylhexyl nitrate production (in Polish). Przemysł Chemiczny, Vol.92, No.4, 2013; pp.463-468

[14] Dias F.F., Oliveira A.A.S., Arcanjo A.P., Moura F.C.C., Pacheco J.G.A.; Residue-based iron catalyst for the degradation of textile dye via heterogeneous photoFenton. Applied Catalysis B: Environmental, Vol.186, 2016; pp.136-142

[15] Asghar A., Raman A., Daud W.; Advanced oxidation processes for in-situ production of hydrogen peroxide/hydroxyl radical for textile wastewater treatment: A review. J. Clean. Prod., Vol.87, 2015; pp.826-838

[16] Barbusinski K.; Modification of Fenton reaction using calcium and magnesium peroxides (monograph in Polish). Prace Naukowe Głównego Instytutu Górnictwa, nr 869. Katowice 2006 (ISSN 1230-2643)

[17] Salwiczek S., Barbusiński K., Dymaczewski Z., Matyska Z., Żołnierczyk M.; Preliminary studies on modified Fenton and UV/H2O2 processes for purification of wastewater from 2-ethylhexyl nitrate production (in Polish). Przemysł Chemiczny, Vol.95, No.1, 2016; pp.118-120 (DOI: 10.15199/62.2016.1.21)

[18] Barbusinski K.; Sodium percarbonate as an agent for effective treatment of industrial wastewater (in Polish). Przemysł Chemiczny, Vol.87, No.1, 2008; pp.33-37

[19] Barbusiński K., Pieczykolan B., Dadał A.; Treatment of dye wastewater by Fenton reagent in modification with sodium percarbonate (in Polish). Gaz Woda i Technika Sanitarna, No.11, 2008; pp.24-26

[20] Barbusiński K., Pieczykolan B.; Preliminary tests of degradation of dye Acid Green 16 in the H2O2/swarf system (in Polish). Inżynieria i Ochrona Środowiska, Vol.12, No.1, 2009; pp.35-49

[21] Pfaltz & Bauer. Safety data sheet. (Date prepared 29.07.2014). www.pfaltzandbauer.com

[22] Ghezzar M.R., Abdelmalek F., Belhadj M., Benderdouche N., Addou A.; Gliding arc plasma assisted photocatalytic degradation of anthraquinonic acid green 25 in solution with TiO2. Applied Catalysis B: Environmental, Vol.72, 2007; pp.304-313

[23] El-Ashtoukhy E-S.Z., Amin N.K.; Removal of acid green dye 50 from wastewater by anodic oxidation and electrocoagulation – A comparative study. J. Hazard. Mat., Vol.179, 2010; pp.113-119

[24] Hameed B.H., Ahmad A.A., Aziz N.; Isotherms, kinetics and thermodynamics of acid dye adsorption on activated palm ash. Chemical Engineering Journal, Vol.133, 2007; pp.195-203

[25] Barbusiński K.; Advanced oxidation in the treatment of selected industrial wastewater Monografia. Wyd. Politechniki Śląskiej, Gliwice 2013 (ISBN 978-83- 7880-101-6) (in Polish)

[26] Kowal A. Świderska-Bróż M.; Oczyszczanie wody (Water treatment). PWN. Warszawa, 2005 (in Polish)

[27] Shu H.-Y., Hsieh W.-P.; Treatment of dye manufacturing plant effluent using an annular UV/H2O2 reactor with multi-UV lamps. Separation and Purification Technology, Vol.51, No.3, 2006; pp.379-386

[28] Shu H.-Y. Chang M.-C.; Decolorization effects of six azo dyes by O3, UV/O3 and UV/H2O2processes. Dyes and Pigments, Vol.65, No.1, 2005; pp.25-31

[29] Liu C.-C., Hsieh Y.-H., Lai P.-F., Li C.-H., Kao C.-L.; Photodegradation treatment of azo dye wastewater by UV/TiO2 process. Dyes and Pigments, Vol.68, No.2-3, 2006; pp.191-195

[30] Shu H.-Y., Chang M.-C.; Decolorization and mineralization of a phthalocyanine dye C.I. Direct Blue 199 using UV/H2O2 process. J. Hazard. Mat., Vol.125, No.1-3, 2005; pp.96-101